The C3N4/AC catalyst was prepared by using the same nitrogen content of cyanamide,thiourea,urea as precursor and activated carbon as the carrier. The reaction performance of C3N4/AC catalyst for the catalytic pyrolysis of 1,2⁃dichloroethane was evaluated by using fixed bed reactor,and the properties of catalyst structure were characterized by SEM,XRD,BET,XPS and TGA. The results showed that the initial activity and selectivity of the catalyst prepared from 0.110 mol precursor were close to 100%,but the stability of the catalyst was different obviously. The catalyst synthesized with urea as precursor had the highest catalyst stability compared with the other two precursors. However,the catalysts synthesized by using low loading of precursors showed differences on the catalytic performance. The structure and morphology of the catalysts with low loading of precursor were investigated. The results showed that when the load was reduced to 0.057 mol,the C3N4/AC catalyst prepared with urea had the highest catalytic activity for dehydrochlorination of 1,2⁃dichloroethane and the best stability.The different morphologies of carbon nitride was synthesized by different precursors. The carbon nitride productivity of thiourea and cyanamide is higher than urea but is more easily to form bulk carbon nitride which will result in poor stability. After all,urea is the optimal precursor for the C3N4/AC catalyst for dehydrochlorination of 1,2⁃dichloroethane.

The ER5356 welded wire was welded under the TIG welding to 5 mm thick 7075-T6 super hard aluminum. The performance and microstructure of the welded joints obtained under different welding processes were analyzed, and the best welding parameters were determined. After solid solution treatment for the specimens, four solid solution temperature and three solid solution time were selected for the experiment. The change law of microstructure and properties of welded joints under different solid solution parameters was studied through macro morphology and metallographic observation, scanning electron microscope, X ray diffraction analysis, tensile test and hardness measurement. The results show that the best welding current is 110 A determined by welding technology, solid solution treatment temperature is 480 ℃, solid solution time is 45 min. At this time, the microstructure of welded joints is improved, and the mechanical properties of the welded joints are better. That is, the size of the grain structure is homogeneous, and the precipitates are dispersed in the matrix and grain boundaries. Thus, more elements are dissolved into the matrix and the grain boundary.

Silicon－containing epoxy resin （CNE －Si） was synthesized from diphenylsiandiol （DPSD） and ortho－cresol novolac epoxy resin with SnCl_２ as catalyst．The chemical structure of CNE－Si prepared was characterized by FT－ IR，^１H －NMR ．The thermal stability was analyzed by TGA．The results show that the －Si－group enhanced the thermal stability of the epoxy resin．The curing kinetics of the system is studied by isothermal DSC．The kinetic parameters of the curing reaction including the activation energy and reaction order are calculated using Kissinger and Ozawa method，which offer basic date for the application of CNE－Si ．